Determination of metallic cobalt in the atmosphere |
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| Authors: | A Profumo G Spini L Cucca M Cantoni E Zecca |
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| Institution: | 1. Dipartimento di Chimica Generate , V.le Taramelli12, Pavia, 27100, Italy;2. Dipartimento di Medicina Preventiva Occupazionale e di Comunità , V.le Taramelli 2, Pavia, 27100, Italy |
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| Abstract: | Due to the fact that, among the different chemical species, metallic cobalt is characterized by the highest toxicity, in this paper is proposed a procedure for its determination in the atmospheric paniculate. The air is filtered on a cellulose or glass fiber membrane, to collect the paniculate containing among the other species, metallic cobalt: the determination is based on a selective dissolution of the metallic cobalt possibly present followed by its determination by atomic absorption spectroscopy. The typical interferences that can be present in the matrix are discussed and suggestions for their minimisation are proposed. By the following procedure is also possible to determine separately the sum of the insoluble and water soluble cobalt compounds. |
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| Keywords: | Cobalt speciation air pollutants |
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