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Distribution of volatile organohalogen compounds in petrochemical plant water streams
Authors:Marek Tobiszewski  Jacek Namie?nik
Institution:1. Department of Analytical Chemistry, Chemical Faculty , Gdańsk University of Technology , Gdańsk , Poland marektobiszewski@wp.pl;3. Department of Analytical Chemistry, Chemical Faculty , Gdańsk University of Technology , Gdańsk , Poland
Abstract:The study assesses halogenated volatile organic compound concentrations in the water and wastewater streams of a petrochemical plant. Water samples were collected at 11 sampling points during 5 sampling campaigns. The samples were collected from the oil dewaxing unit and in the wastewater treatment plant. Dichloromethane and 1,2-dichloroethane were the most frequently determined compounds. Tetrachloroethene was also detected at the wastewater treatment plant inlets. The concentrations of halogenated volatile organic compounds dropped significantly at wastewater discharge points compared to wastewater treatment plant inlets. The application of 1,2-dichloroethane/dichloromethane ratio as a tool to assess evaporation processes is discussed.
Keywords:wastewater  chlorinated solvents  water quality
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