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Polycyclic aromatic hydrocarbons in surface sediments held in experimental mesocosms
Authors:Richard J Pruell  James G Quinn
Institution:1. Graduate School of Oceanography , University of Rhode Island , Narragansett, Rhode Island, 02882, U.S.A.;2. Environmental Research Laboratory , Science Applications International Corporation, c/o U.S. Environmental Protection Agency , Narragansett, Rhode Island, 02882, U.S.A.;3. Graduate School of Oceanography , University of Rhode Island , Narragansett, Rhode Island, 02882, U.S.A.
Abstract:Sediment was collected from three locations along a pollution gradient in Narragansett Bay and transplanted to controlled mesocosms. Total hydrocarbons and eleven individual polycyclic aromatic hydrocarbons (PAHs) were measured in these sediments over a period of 394 days. Total hydrocarbon concentrations increased in the “relatively uncontaminated”; (Rhode Island Sound) sediment that was held in the mesocosms, but did not change in the two other sediments. The concentrations of four PAHs: naphthalene, 2‐methyl naphthalene, 1‐methyl naphthalene and biphenyl, decreased in the “contaminated”; (Providence River) sediment during the experiment and the calculated half‐lives for these compounds were 287, 353, 321 and 333 days, respectively.
Keywords:Fluorinated pilocarpine analogs  synthesis  cholinergic properties  fluoropilocarpine analogs SAR‐receptor site  fluoroquaternary pilocarpine analogs  biological activity
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