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Removal of citrate and hypophosphite binary components using Fenton, photo-Fenton and electro-Fenton processes
Authors:Yao-Hui Huang  Hsiao-Ting Su and Li-Way Lin
Institution:1. Department of Chemical Engineering, “National” Cheng Kung University, Tainan 701, Taiwan, China;2. Sustainable Environment Research Center, Tainan 701, Taiwan, China
Abstract:Both citrate and hypophosphite in aqueous solution were degraded by advanced oxidation processes (Fe2+/H2O2, UV/Fe2+/H2O2, and electrolysis/ Fe2+/H2O2) in this study. Comparison of these techniques in oxidation efficiency was undertaken. It was found that Fenton process could not degrade completely citrate in the presence of hypophosphite since it caused a series inhibition. Therefore, UV light (photo-Fenton) or electron current (electro-Fenton) was applied to improve the degradation efficiency of the Fenton process. Results showed that both photo-Fenton and electro-Fenton processes could overcome the inhibition of hypophosphite, especially the electro-Fenton.
Keywords:citrate  hypophosphite  wastewater  advanced oxidation processes  Fenton  photo-Fenton  electro-Fenton
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