Fluorescence fingerprints to monitor total trihalomethanes and N-nitrosodimethylamine formation potentials in water |
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Authors: | Bin Hua Kristen Veum Amod Koirala John Jones Thomas Clevenger Baolin Deng |
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Institution: | (1) Department of Civil and Environmental Engineering, University of Missouri, Columbia, MO 65211, USA;(2) Department of Fisheries & Wildlife Sciences, University of Missouri, Columbia, MO 65211, USA |
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Abstract: | Water samples from 56 lakes of Missouri, USA, were analysed for their fluorescence excitation/emission matrix (EEM) spectroscopy
and the formation potentials of total trihalomethanes (TTHM) and N-nitrosodimethylamine (NDMA). Comparing the excitation/emission matrix fingerprints with trihalomethanes formation revealed
that water with higher fluorescence intensity generally exhibited higher trihalomethanes formation potential. Moreover, waters
with fluorescence centre at excitation: 290–310 nm/emission: 330–350 nm were related to high N-nitrosodimethylamine and trihalomethanes formation potentials. The results suggest that excitation/emission matrix fingerprints
could be used as surrogate parameters for monitoring trihalomethanes and N-nitrosodimethylamine formation potentials. |
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Keywords: | Fluorescence spectroscopy Excitation/emission matrix Disinfection by-products |
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