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石灰沉淀法除砷的影响因素
引用本文:黄自力,刘缘缘,陶青英,耿晨晨,何甜辉.石灰沉淀法除砷的影响因素[J].环境工程学报,2012,6(3):734-738.
作者姓名:黄自力  刘缘缘  陶青英  耿晨晨  何甜辉
作者单位:武汉科技大学冶金矿产资源高效利用与造块湖北省重点实验室,武汉,430081
基金项目:国家自然科学基金资助项目(50904047)
摘    要:以Ca(OH)2溶液为沉淀剂,处理模拟含砷废水砷酸钠溶液,考察了pH值、Ca/As摩尔比、自由沉降时间和反应温度等因素对石灰沉淀法除砷效果的影响。结果表明,在pH值为12,Ca/As摩尔比为6,沉降时间为48 h,反应温度为25℃时,石灰沉淀法除砷的效率可达到99.05%;此外,对高浓度的含砷废水,在石灰沉淀法除砷工艺中添加简单无机盐絮凝工艺,可显著降低出水总砷浓度,达到污水综合排放标准的要求。

关 键 词:石灰沉淀  pH值  Ca/As摩尔比  无机絮凝剂
收稿时间:9/3/2010 12:00:00 AM

Influencing factors of arsenic removal by lime precipitation
Huang Zili,Liu Yuanyuan,Tao Qingying,Geng Chenchen and He Tianhui.Influencing factors of arsenic removal by lime precipitation[J].Techniques and Equipment for Environmental Pollution Control,2012,6(3):734-738.
Authors:Huang Zili  Liu Yuanyuan  Tao Qingying  Geng Chenchen and He Tianhui
Institution:Huang Zili Liu Yuanyuan Tao Qingying Geng Chenchen He Tianhui(Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Resources, Wuhan University of Science and Technology,Wuhan 430081,China)
Abstract:With the Ca(OH)2 solution for precipitation agent and the sodium arsenate solution for simulation arsenic water,the effects of pH,the Ca/As molar rations,the precipitate time and the temperature on arsenic removal by lime precipitation were studied.The results showed that,while controlling the pH was 12,the mole ratio of Ca/As was 6,the time of precipitate was 48 hours and the temperature was 25 ℃,the removal rate of arsenic rose to 99.05%.Besides,when adding the inorganic flocculants to high concentration of arsenic wastewater treated with Ca(OH)2 solution,the effluent concentration of arsenic wastewater could be significantly reduced,then met the requirements of integrated wastewater discharge standard.
Keywords:lime precipitation  pH  Ca/As molar ratios  inorganic flocculant
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