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| 电-Fenton法处理制药中间体废水的研究 | |
| 引用本文： | 谢清松,张艳,李瑞萍,张艺,黄应平,李莉娥.电-Fenton法处理制药中间体废水的研究[J].环境工程学报,2010,4(1):57-62. |
| 作者姓名： | 谢清松 张艳 李瑞萍 张艺 黄应平 李莉娥 |
| 作者单位： | 1. 三峡大学Alan G.MacDiarmid再生能源研究所,宜昌,443002 2. 三峡大学Alan G.MacDiarmid再生能源研究所,宜昌,443002;三峡库区生态环境教育部工程研究中心,宜昌,443002 3. 宜昌人福药业有限公司,宜昌,443002 |
| 基金项目： | 湖北省教育厅优秀中青年科技创新团队计划项目（T200703）；宜昌市科技发展计划项目（A06104） |
| 摘 要： | 采用电-Fenton法对麻醉药瑞芬太尼合成过程中的中间体1-苄基-4-氨甲酰基-4-苯胺基哌啶(简称酰胺,AMIDE)模拟废水进行了降解研究,结果表明,在以石墨为阴极、铁为阳极的模式下,当pH为3、电解电压为3 V、投加H_2O_2浓度为10 mmol/L时,室温下电解浓度为20 mg/L的酰胺废水60 min后,酰胺的去除率高于99%,TOC去除60%。通过紫外光谱(UV)、红外光谱(IR)及HPLC检测酰胺的降解产物,说明电-Fenton法能使废水中目标化合物的环结构破坏,快速而完全地转化为小分子,但不能使其全部矿化。本研究可为电-Fenton法在处理该类药物合成废水中的实际应用提供重要的理论依据。 |
| 关 键 词： | 电-Fenton法 阳极氧化 制药废水 降解 |
| 修稿时间： | 2/8/2009 12:00:00 AM |
Study on treatment of pharmaceutical wastewater from intermediate synthetic process by electro-Fenton oxidation |
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| Xie Qingsong,Zhang Yan,Li Ruping,Zhang Yi,Huang Yingping and Li Lie.Study on treatment of pharmaceutical wastewater from intermediate synthetic process by electro-Fenton oxidation[J].Techniques and Equipment for Environmental Pollution Control,2010,4(1):57-62. | |
| Authors: | Xie Qingsong Zhang Yan Li Ruping Zhang Yi Huang Yingping and Li Lie |
| Institution: | 1.Alan G. MacDiarmid Research Institute of Renewable Energy, China Three Gorges University,Yichang 443002,China,1.Alan G. MacDiarmid Research Institute of Renewable Energy, China Three Gorges University,Yichang 443002,China,1.Alan G. MacDiarmid Research Institute of Renewable Energy, China Three Gorges University,Yichang 443002,China;2.Engineering Research Center of Eco-Environment in Three Gorges Reservoir Region,Ministry of Education,Yichang 443002,China,1.Alan G. MacDiarmid Research Institute of Renewable Energy, China Three Gorges University,Yichang 443002,China,1.Alan G. MacDiarmid Research Institute of Renewable Energy, China Three Gorges University,Yichang 443002,China;2.Engineering Research Center of Eco-Environment in Three Gorges Reservoir Region,Ministry of Education,Yichang 443002,China and 3. Yichang Humanwell Pharmaceutical Co. Ltd., Yichang 443002,China |
| Abstract: | An electro-Fenton method was investigated for the treatment of pharmaceutical wastewater from intermediate i.e.1-benzyl-4-carbamoyl-4-anilinopiperidine(ab.AMIDE) synthetic process using a graphite cathode and a Fe anode.The factors affecting the removal efficiency of AMIDE has been optimized.The results showed that the optimal conditions were as follows:room temperature,initial pH 3,AMIDE concentration of 20 mg/L,electrolytic voltage of 3 V,dosage of H_2O_2 of 10 mmol/L and reaction duration of 60 min.Under... |
| Keywords: | electro-Fenton anodic oxidation pharmaceutical wastewater degradation |
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