| 过渡金属催化剂对邻二氯苯的催化氧化研究 |
| |
| 引用本文： | 崔龙哲,丁泰燮,尹炳硕.过渡金属催化剂对邻二氯苯的催化氧化研究[J].环境科学与技术,2004,27(5):22-23,47. |
| |
| 作者姓名： | 崔龙哲 丁泰燮 尹炳硕 |
| |
| 作者单位： | 中南民族大学化学与生命科学学院,430074;全北国立大学校环境工学科,韩国;全北国立大学校环境工学科,韩国 |
| |
| 摘 要： | 以过渡金属的氧化物制得催化剂系列 ,研究其对邻二氯苯的氧化活性 ,考察反应温度、催化剂负载量、空间速度对氧化过程的影响 ,过渡金属氧化物对邻二氯苯的氧化活性顺序为 :CrOx>CuOx >VOx >MnOx >MoOx。 5wt.%V 1 0wt.%Mo3wt.%Mn/Al2 O3催化剂在 350℃时对邻二氯苯转换率达到了 90 %以上。
|
| 关 键 词： | 催化氧化 邻二氯苯 过渡金属 |
| 文章编号： | 1003-6504(2004)05-0022-03 |
Catalytic Oxidation of O-dichlorobenzene Using Transition Metal Oxides as Catalysts |
| |
| CUI Long-zhe.Catalytic Oxidation of O-dichlorobenzene Using Transition Metal Oxides as Catalysts[J].Environmental Science and Technology,2004,27(5):22-23,47. |
| |
| Authors: | CUI Long-zhe |
| |
| Institution: | CUI Long-zhe~ |
| |
| Abstract: | This paper describes an experiment conducted to investigate the effects of reaction temperature, catalytic carrier and space velocity on oxidation of o-dichlorobenzene using catalysts which are made of several transition metal oxides. Activity of the different transition metal oxides for o-dichlorobenzene oxidation was tested. It was showed that with the catalyst (5wt. %V-10wt. % MnO_(3)- 3wt. % Mn/Al_(2)O_(3)), more than 90% conversion of o-dichlorobenzene is achieved at 350℃. |
| |
| Keywords: | catalytic oxidation o-dichlorobenzene transition metal |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
