Application of Infrared Spectroscopy to Exhaust Gas Analysis

Abstract

The Mohave Valley region of southern Nevada/southwestern Arizona has experienced elevated particulate concentrations and is classified as a PM₁₀ nonattainment area. Anthropogenic aerosol sources in the area include the Mohave Power Project (MPP), a 1,580-MW coal-fired power plant; motor vehicles; construction activities; and paved and unpaved road dust and disturbed desert soil. Aerosols may also be transported long distances from other areas, such as the Los Angeles Basin. Based on the infrequency of plume contact at sites in the valley (as determined by SO₂ measurements), it was believed that the contribution of the MPP to primary PM₁₀ was minimal and that fugitive dust was the primary source of ambient particulate matter.

To evaluate the magnitude of source contributors, PM₁₀ measurements were made using a medium-volume sampler along with ancillary meteorological and air quality measurements in the Mohave Valley at Bullhead City, Arizona, for a period of longer than one year (September 1988 through mid-October 1989). The aerosol filter samples were analyzed for mass, elements, ions, and carbon. Source apportionment using the Chemical Mass Balance (CMB) receptor model was performed. On average, geological dust was the major contributor to PM10 (79.5%), followed by primary motor vehicle sources (16.7%), secondary ammonium sulfate (3.5%), secondary ammonium nitrate (0.1%), and primary coal-fired power plant emissions (0.1%).