Assessment of dissolved heavy metal in the Yangtze River estuary and its adjacent sea, China

The purpose of this paper is to determine the concentrations of dissolved heavy metals namely mercury (Hg), lead (Pb), cadmium (Cd), and copper (Cu) and to investigate the relationships between nutrients (nitrate-nitrogen and phosphate) and dissolved heavy metals. For this purpose, the concentrations of dissolved heavy metals were measured through 51 voyages form 1984 to 2006 in the Yangtze river estuary and its adjacent sea. Results analysis showed that dissolved heavy metals were not the main pollutants in the Yangtze river estuary, and the main source of heavy metal contamination was industrial wastewater from terrestrial pollution during the past 20 years. Heavy metal values showed significant abundance in the south branch of the Yangtze River estuary and Hangzhou Bay. In addition, Pb showed negative correlation with nutrients, while the positive correlations between Hg, Cd, and nutrients were shown. The obtained molar ratios, $Delta mbox{Cd}/Delta mbox{N} = 1.68 times 10^{-5}$ and $Delta mbox{Cd}/Delta mbox{P} = 1.66 times 10^{-4}$ , are close to those in plankton, showing the biogeochemical behavior and process of dissolved cadmium.