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珠江入海口水体中多溴联苯醚及其来源分析
引用本文:管玉峰,涂秀云,吴宏海.珠江入海口水体中多溴联苯醚及其来源分析[J].生态环境,2011,20(3):474-479.
作者姓名:管玉峰  涂秀云  吴宏海
作者单位:1. 华南师范大学化学与环境学院,广东,广州,510635;中国科学院广州地球化学研究所∥有机地球化学国家重点实验室,广东,广州,510640
2. 华南师范大学化学与环境学院,广东,广州,510635
基金项目:国家自然科学基金项目,中科院广州地化所有机地球化学国家重点实验室项目
摘    要:2005年3月至2006年2月,选取珠江8个入海口,进行每月1次为期1周年的水样采集。检测了96个水样的多溴联苯醚(PBDEs,包括BDE 28、47、66、85、99、100、138、153、154、183、196、197、203、206、207、208和209)的残留状况。水体中PBDEs的质量浓度为0.344~68.0 ng·L-1。PBDEs的组成分析结果表明:珠江水体PBDEs的来源以土壤和沉积物源为主,而目前珠三角陆地环境中PBDEs仍不断蓄积,其通过珠江地表径流迁移转换的PBDEs将逐年增多,给珠三角水生态环境带来的压力逐日增加,所造成的生态环境及公众健康影响将是深远的。

关 键 词:多溴联苯醚  河流径流  珠三角  污染源

Distribution and source of polybrominated diphenyl ethers (PBDEs)in riverine water of the Pearl River Delta
GUAN Yufeng,TU Xiuyun,WU Honghai.Distribution and source of polybrominated diphenyl ethers (PBDEs)in riverine water of the Pearl River Delta[J].Ecology and Environmnet,2011,20(3):474-479.
Authors:GUAN Yufeng  TU Xiuyun  WU Honghai
Institution:GUAN Yufeng1,2,TU Xiuyun1,WU Honghai1 1.School of Chemistry and Environment,South China Normal University,Guangzhou 510635,China,2.State Key Laboratory of Organic Geochemistry//Guangzhou Institute of Geochemistry,Chinese Academy of Sciences,Guangzhou 510640
Abstract:A large-scale sampling program was conducted to collect water samples at eight major riverine runoff outlets of the Pearl River Delta(PRD) monthly from March 2005 to February 2006.Ninety-six water samples were measured for PBDEs(sum of 17 BDE congeners,i.e.,BDE 28,47,66,85,99,100,138,153,154,183,196,197,203,206,207,208,and 209),and the PBDEs concentrations were 0.344-68.0 ng·L-1.Results from compositional profiles indicated that soil and sediments are the main sources of PDBDEs in the water body of the Pearl River.Furthermore,the study also found that PBDEs in the terrestrial environment of the Pearl River Delta continued to accumulate,and the yearly input of PBDEs into Pearl River from surface runoff continues to increase,putting more and more stress on the water ecological environment;as a result,the impact of PBDE on the environment and human health is expected to persist for many years to come.
Keywords:PBDEs  riverine water  the Pearl River Delta  source  
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