多因素综合海洋气候自然加速试验技术相关性和加速性验证

目的对新研发的多因素综合海洋气候环境自然加速试验技术相对热带海洋气候环境户外暴露试验的相关性和加速性进行验证。方法分别采用多因素综合海洋气候环境自然加速试验装置和对应的试验方法企业标准,以及传统的户外暴露试验方法,以不同表面处理工艺的汽车紧固件、标准金属、有机涂层和塑料为样品进行验证试验,采用Spearman秩相关系数法和加速因子(AF)法对相关性和加速性进行进一步验证。结果紧固件、标准金属和有机涂层在多因素综合海洋气候环境自然加速试验和海洋气候环境户外暴露试验过程中,都表现出相同的腐蚀失效模式。多因素综合海洋气候环境自然加速试验相对远海场(离海岸线350 m)户外暴露试验紧固件秩相关系数为1,镀锌镍合金紧固件、无铬锌铝涂层紧固件、拉弗莱紧固件和石墨烯紧固件的加速倍率分别为7.7,11.3,10.3,13.5倍;标准金属秩相关系数为0.8,Q235、工业纯铝、工业纯锌和工业纯铜的加速倍率分别为11.8,11.5,9.3,3.7倍。多因素综合海洋气候环境自然加速试验相对海洋平台户外暴露试验标准金属秩相关系数为1,Q235、工业纯铝、工业纯锌和工业纯铜的加速倍率分别为3.4,2.1,4.5,2.2倍。结论多因素综合海洋气候环境自然加速试验相对海洋气候环境户外暴露试验具有良好的相关性,而且对海洋平台的相关性更好。对于紧固件表面处理工艺、标准金属和有机涂层而言,多因素综合海洋气候环境自然加速试验相对海洋气候环境户外暴露试验具有高的加速倍率。

Relativity and Acceleration Verification of Multi-factors Integrated Marine Climate Natural Accelerated Test Technologies

Objective To verify the relativity and acceleration of multi-factors integrated marine climate natural accelerated test technologies to outdoor exposure test in tropic marine climate.Methods Multi-factors integrated marine climate natural ac-celerated test device, relative enterprise standards as well as traditional marine climate outdoor exposure were adopted to test and verify automobile fasteners of different surface treatment technologies, standard metals, organic coatings and plastics as specimen. Spearman order relativity coefficient method and acceleration factor method were used to further verify the relativity and acceleration.Results Automobile fasteners, standard metals and organic coatings indicated that their corrosion failure mod-es were the same in multi-factors integrated marine climate natural accelerated test and tropic marine climate outdoor exposure test. For the accelerated test to outdoor exposure test in the exposure site 350 meters from South China Sea, order relativity coefficient of fasteners was 1, and the acceleration rate of zinc nickel alloy plated fastener, chromium free zinc aluminum alloy coated fastener, LAFRE coated fastener and Graphene coated fastener was 7.7, 11.3, 10.3 and 13.5 respectively; order relativity coefficient of standard metals was 0.8, and the acceleration rate of Q235, industrial pure aluminum, industrial pure zinc, and in-dustrial pure copper was 11.8,11.5,9.3 and 3.7 respectively. For the accelerated test to outdoor exposure test in the marine plat-form, order relativity coefficient of standard metals was 1, and the acceleration rate of Q235, industrial pure aluminum, industri-al pure zinc, and industrial pure copper was 3.4, 2.1, 4.5 and 2.2 respectively.Conclusion Multi-factors integrated marine cli-mate natural accelerated test technology has good relativity to tropic marine climate outdoor exposure, and has better relativity to marine platform exposure. The technology also has high acceleration rate to traditional marine climate outdoor exposure for surface treatment technologies of automobile fasteners, standard metals and organic coating.