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成型膨润土和钛柱撑膨润土对水中Pb2+和氯乙酸吸附及再生
引用本文:陈学青, 曹吉林, 侯丽红, 谭朝阳. 成型膨润土和钛柱撑膨润土对水中Pb2+和氯乙酸吸附及再生[J]. 环境工程学报, 2007, 1(5): 36-40.
作者姓名:陈学青  曹吉林  侯丽红  谭朝阳
作者单位:1.河北工业大学化工学院,天津 300130
摘    要:针对水中微量铅离子和氯乙酸的脱除,考察了成型膨润土及成型钛柱撑膨润土的吸附性能,得出对铅离子的吸附,成型膨润土、成型钛柱撑膨润土与粉末状活性炭性能相当,而对氯乙酸的吸附前两者要比粉末状活性炭低好多。确定了成型膨润土吸附氯乙酸后可用沸水煮沸30 min的方法再生,成型钛柱撑膨润土吸附氯乙酸后,可用500℃焙烧3 h的方法再生,再生的膨润土循环使用3次后性能降低明显。此外,还测得了成型的膨润土及成型的钛柱撑膨润土吸附铅离子和氯乙酸的等温线,计算出其对铅的最大吸附量分别为24.33 mg/g和15.47 mg/g。

关 键 词:成型膨润土   成型钛柱撑膨润土   吸附   铅离子   氯乙酸
收稿时间:2007-04-01

Sorption of Pb2+ and chloroactic in solution on molding bentonite and molding Ti-pillared bentonite and their regeneration
Chen Xueqing, Cao Jilin, Hou Lihong, Tan Zhaoyang. Sorption of Pb2+ and chloroactic in solution on molding bentonite and molding Ti-pillared bentonite and their regeneration[J]. Chinese Journal of Environmental Engineering, 2007, 1(5): 36-40.
Authors:Chen Xueqing  Cao Jilin  Hou Lihong  Tan Zhaoyang
Affiliation:1.School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130
Abstract:In view of the removal of small lead ionic and chloroactic in solution, the adsorption of molding bentonite and molding Ti-pillared bentonite are determined.It is concluded that the adsorption capability of molding Ti-pillared bentonite is equal to active carbon for lead ionic, their adsorption capability for chloroactic is much lower than active carbon. The regeneration mehod of molding benotine is that after adsorption chloroactic is boiled in water for 30 minutes. The regeneration mehod of molding Ti-pillared bentonite is that it is canclined at 500℃ for 3 h. The regenerative molding Ti-pillared bentonite can be used three times and their adsorption capability is reduced significantly after three times. Moreover, the sorption isotherm for chloroacetic acid and lead ionic on molding bentonite and molding Ti-pillared bentonite are determined,the max adsorption mass for lead ionic are 24.33 mg/g and 15.47 mg/g separatively。
Keywords:molding bentonite  molding Ti-pillared bentonite  adsorption  lead ionic  chloroacetic acid
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