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Characterization of As and trace metals embedded in PM10 particles in Puebla City, México
Authors:S S Morales-García  P F Rodríguez-Espinosa  M P Jonathan  M Navarrete-López  M A Herrera-García  N P Muñoz-Sevilla
Institution:1. Centro Interdisciplinario de Investigaciones y Estudios sobre Medio Ambiente y Desarrollo (CIIEMAD), Instituto Politécnico Nacional (IPN), Calle 30 de Junio de 1520, Barrio la Laguna Ticomán, Del. Gustavo A. Madero, 07340, México, DF, México
2. Escuela Superior de Ingeniería Química e Industrias Extractivas (ESIQIE), Instituto Politécnico Nacional (IPN), Edificio 7 Unidad Profesional Adolfo López Mateos, Colonia La Escalera, Del Gustavo A. Madero, 07738, México, DF, Mexico
3. Escuela Nacional de Ciencias Biológicas, Laboratorio Central de Instrumentación, Instituto Politécnico Nacional (IPN), Prol. de Manuel M Carpio y Plan de Ayala, Col. Sto. Tomas, Del. Miguel Hidalgo, 11340, México, DF, México
4. Secretaria del Medio Ambiente y Recursos Naturales del Estado de Puebla (SMRN), Calle 33 Sur No. 3512 Col. El Vergel, 72400, Puebla, México
5. Universidad Autónoma de Tlaxcala (UAT), Av. Universidad No. 1, Col. Loma Xicohténcatl, 90070, Tlaxcala, México
Abstract:Forty-eight air-filter samples (PM10) were analysed to identify the concentration level of partially leached metals (PLMs; As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and V) from Puebla City, México. Samples were collected during 2008 from four monitoring sites: (1) Tecnológico (TEC), (2) Ninfas (NIN), (3) Hermanos Serdán (HS) and (4) Agua Santa (AS). The results indicate that in TEC, As (avg. 424 ng m?3), V (avg. 19.2 ng m?3), Fe (avg. 1,202 ng m?3), Cu (avg. 86.6 ng m?3), Cr (41.9 ng m?3) and Ni (18.6 ng m?3) are on the higher side than other populated regions around the world. The enrichment of PLMs is due to the industrial complexes generating huge dust particles involving various operations. The results are supported by the correlation of metals (Mn, Cd and Co) with Fe indicating its anthropogenic origin and likewise, As with Cd, Co, Fe, Mn, Pb and V. The separate cluster of As, Fe and Mn clearly signifies that it is due to continuous eruption of fumaroles from the active volcano Popocatépetl in the region.
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