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Predictions of evaporative loss rates of solutes in stagnant and turbulent waters in relation to rates of reference materials
Authors:Carty T Chiou  Rodger L Kohnert  Virgil H Freed  Russell G Tonkyn
Institution:Environmental Health Sciences Center and Department of Agricultural Chemistry, Oregon State University, Corvallis, Oregon 97331, USA
Abstract:A previously published kinetic model for evaporative rates of substances into air leads to the estimation of the dependence of solute transfer coefficients on turbulence to the system. The ratios of the transfer coefficients of all solutes become insensitive to air turbulence and to water mixing either when they have comparable Henry's law constants or when their Henry's law constants are sufficiently low, but not otherwise. Confirming data are presented and methods for simplifying the estimation of transfer coefficients are discussed.
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