Polar organic pollutants in air: A review of collection and analysis

Pollutants which are capable of being extracted into nonpolar solvent such as hexane have received the greatest attention in environmental monitoring. However, the polar fraction, inherently more difficult to analyze, is currently undergoing closer scrutiny. Sampling methods specifically designed to entrap polar particles and vapors are compared. Ion-exchange and reversed-phase liquid chromatography columns are examples of such specific sampling techniques. Various extraction schemes are presented with their individual problems and capabilities. Although there are numerous papers on the analysis of polar organic pollutants, few report actual measurements of ambient air samples. Current reports on polar organic pollutants measured in air samples are summarized. Polar organics are generally divided into three categories: acidic, basic, and neutral. Analytical methods relating to the following categories of polar organic compounds are reviewed: (1) phenols, mono- and dicarboxylic acids, and sulfonic acids, (2) aliphatic and aromatic amines, and (3) alcohols, aldehydes and ketones, phthalate esters, isocyanates and N-nitrosamines. Derivatization techniques, such as ester formation, are compared to the analysis of the unsubstituted compound. The formation of such derivatives is often the best way to trace specific compounds at very low levels.