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Application of activated carbon derived from scrap tires for adsorption of Rhodamine B
Authors:Li Li  Shuangxi Liu and Tan Zhu
Institution:1. Institute of New Catalytic Materials Science,College of Chemistry,Nankai University,Tianjin 300071,China
2. College of Environmental Science and Engineering,Nankai University,Tianjin 300071,China
Abstract:Activated carbon derived from solid hazardous waste scrap tires was evaluated as a potential adsorbent for cationic dye removal. The adsorption process with respect to operating parameters was investigated to evaluate the adsorption characteristics of the activated pyrolytic tire char (APTC) for Rhodamine B (RhB). Systematic research including equilibrium, kinetics and thermodynamic studies was performed. The results showed that APTC was a potential adsorbent for RhB with a higher adsorption capacity than most adsorbents. Solution pH and temperature exert significant influence while ionic strength showed little e ect on the adsorption process. The adsorption equilibrium data obey Langmuir isotherm and the kinetic data were well described by the pseudo second-order kinetic model. The adsorption process followed intra-particle di usion model with more than one process a ecting the adsorption process. Thermodynamic study confirmed that the adsorption was a physisorption process with spontaneous, endothermic and random characteristics.
Keywords:activated pyrolytic tire char  Rhodamine B  adsorption isotherm  thermodynamics
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