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“氧化镁/活性炭”新型吸附剂的制备及其对Cr(Ⅵ)的吸附研究
引用本文:侯少芹,王海增,孙金香,孙宝维,朱培怡.“氧化镁/活性炭”新型吸附剂的制备及其对Cr(Ⅵ)的吸附研究[J].环境污染治理技术与设备,2009(12):2133-2137.
作者姓名:侯少芹  王海增  孙金香  孙宝维  朱培怡
作者单位:中国海洋大学化学化工学院,海洋化学理论与工程技术教育部重点实验室,青岛266100
基金项目:国家自然科学基金资助项目(20477041)
摘    要:以氯化镁和造纸草浆黑液为原料,采用物理活化法制得"氧化镁/活性炭"新型吸附剂,其比表面积(BET)为388.96 m2/g、总孔容积为0.40 mL/g。测定了这种吸附剂对水中Cr(Ⅵ)的吸附性能,考察了吸附时间、pH值、吸附剂投加量、初始浓度等因素对Cr(VI)的吸附量和脱除率的影响,研究所得吸附水溶液中Cr(Ⅵ)的最佳条件为:吸附时间为120min,吸附剂投加量为2 g/L,pH值为2。"氧化镁/活性炭"新型吸附剂对Cr(Ⅵ)的吸附过程符合Freundlich等温式。

关 键 词:造纸黑液  “氧化镁/活性炭”  Cr(Ⅵ)  吸附

Preparation of "MgO/AC" and its adsorption properties of Cr(Ⅵ)
Hou Shaoqin Wang Haizeng Sun Jinxiang Sun Baowei Zhu Peiyi.Preparation of "MgO/AC" and its adsorption properties of Cr(Ⅵ)[J].Techniques and Equipment for Environmental Pollution Control,2009(12):2133-2137.
Authors:Hou Shaoqin Wang Haizeng Sun Jinxiang Sun Baowei Zhu Peiyi
Institution:Hou Shaoqin Wang Haizeng Sun Jinxiang Sun Baowei Zhu Peiyi ( Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China)
Abstract:A noval adsorbent from straw pulp black liquor and magnesia chloride was made by physical activation.The results show that the BET surface and total pore volume reach 388.96 m2/g and 0.40 mL/g respectively.The effects of adsorption time,pH,adsorbent dosage and initial concentration were investigated.The best absorption effect was acquired at pH value 2,adsorbent dosage 2 g/L,adsorption time 120 min.The adsorption of Cr(Ⅵ) follows Freundlich isotherm.
Keywords:straw pulp black liquor  "MgO/AC"  Cr(Ⅵ)  adsorption
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