| 间位羟基/甲氧基多溴联苯醚的合成 |
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| 引用本文： | 曹洁,郑裕义,高丽萍,余海雯,郑柯文. 间位羟基/甲氧基多溴联苯醚的合成[J]. 环境化学, 2009, 28(6): 893-898 |
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| 作者姓名： | 曹洁 郑裕义 高丽萍 余海雯 郑柯文 |
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| 作者单位： | 上海大学环境与化学工程学院,环境污染与健康研究所,上海,200444;上海大学环境与化学工程学院,环境污染与健康研究所,上海,200444;上海大学环境与化学工程学院,环境污染与健康研究所,上海,200444;上海大学环境与化学工程学院,环境污染与健康研究所,上海,200444;上海大学环境与化学工程学院,环境污染与健康研究所,上海,200444 |
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| 摘 要： | 本文设计了3种合成路线,通过偶合反应、Baeyer-Villiger氧化水解、硝基还原、加溴反应、去甲基化等一系列反应,合成了多种间位羟基/甲基多溴联苯醚.产物经过气相色谱-质谱仪(GC-MS)和核磁共振测试表明实验所合成得到的产物与设计的目标产物结构完全一致,其纯度达到标样要求.
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| 关 键 词： | 间位羟基/甲氧基多溴联苯醚 合成 标准样品. |
SYNTHESIS OF META-HYDROXYLATED AND METHOXYLATED POLYBROMINATED DIPHENYL ETHERS |
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| CAO Jie,ZHENG Yu-yi,GAO Li-ping,YU Hai-wen,ZHENG Ke-wen. SYNTHESIS OF META-HYDROXYLATED AND METHOXYLATED POLYBROMINATED DIPHENYL ETHERS[J]. Environmental Chemistry, 2009, 28(6): 893-898 |
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| Authors: | CAO Jie ZHENG Yu-yi GAO Li-ping YU Hai-wen ZHENG Ke-wen |
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| Abstract: | The aim of the present study was to synthesize meta-OH/MeO-PBDEs. Three synthetic schemes have been designed via a trail of reactions including coupling, oxidation hydrolysis, nitro reduction, bromination, demethylation etc. The products were characterized by GC-MS and ~1H NMR spectroscopy, which shows the purity meets the requirement and the chemicals conform are to the expected structures. |
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| Keywords: | meta-hydroxylated and methoxylated polybrominated diphenyl ether (meta-OH/MeOPBDEs) synthesis standard samples. |
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