The equilibrium of ammonium chloride aerosol with gaseous hydrochloric acid and ammonia under tropospheric conditions |
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| Institution: | 1. Department of Chemical Engineering, Tarbiat Modares University, Tehran, Iran;2. Department of Chemical Engineering, Babol Noshirvani University of Technology, Babol, Iran;1. Department, of Mechanical Engineering, High Temperature Research Centre (Coventry), University of Birmingham, UK;2. Department of Mechanical Engineering, Indian Institute of Information Technology Design & Manufacturing, Kancheepuram, Vandalur-Kelambakkam Road, Chennai, 600127, Tamilnadu, India;1. Konotop Institute, Sumy State University, Myru Ave. 24, UA-41600 Konotop, Ukraine;2. Sumy State University, Rimsky-Korsakov Str. 2, UA-40007 Sumy, Ukraine;3. Institute of Physics of National Academy of Sciences of Ukraine, Nauky Ave. 46, UA-03028 Kyiv, Ukraine;4. Institute of Applied Physics of National Academy of Sciences of Ukraine, Petropavlivska Str. 58, UA-40030 Sumy, Ukraine;1. University of Concepción, Faculty of Physical and Mathematical Sciences, PO Box 160-C, Concepción, Chile;2. University Andrés Bello, Faculty of Exact Sciences, Department of Physics, República 220, Santiago, Chile;3. University of La Serena, Faculty of Engineering, Department of Mechanical Engineering, Casilla 554, La Serena, Chile;4. Center for Technological Information, c/Monseñor Subercaseaux 667, La Serena, Chile;1. Petroleum Chemistry Research Group, Department of Pure and Industrial Chemistry, University of Port Harcourt, Port Harcourt, Nigeria;2. Centre for Petroleum Geosciences, Institute of Petroleum Studies, University of Port Harcourt, Port Harcourt, Nigeria;3. Department of Petroleum Engineering, Niger Delta University, Amassoma, Bayelsa State, Nigeria |
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| Abstract: | Using thermodynamic data, the equilibrium constant for dissociation of solid ammonium chloride aerosol into gaseous hydrogen chloride and ammonia has been calculated. The existence of solid ammonium chloride aerosols is thermodynamically possible at temperatures and concentrations observed in the troposphere, but significant gas phase concentrations of hydrogen chloride and ammonia will also be present. |
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