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磺化酞菁铁的合成与光催化降解染料废水的研究
引用本文:王灶生,许宜铭.磺化酞菁铁的合成与光催化降解染料废水的研究[J].上海环境科学,2001,20(10):480-481.
作者姓名:王灶生  许宜铭
作者单位:王灶生(浙江大学化学系,杭州 310027);许宜铭(浙江大学化学系,杭州 310027)
摘    要:采用邻苯二氰方法合成了酞菁铁(FePc)配合物,后又经碘化得磺化酞菁铁(FePcSx),以其作为催化剂利用过氧化氢(H2O2)对模拟染料废水活性艳红X-3B进行光催化降解脱色试验(λ>320nm),结果染料废水的降解脱色率较高。并且通过与单独用过氧化氢降解进行对照,表明磺化酞菁铁具有很好的催化活性与优良的化学结构。

关 键 词:磺化酞菁铁  合成  光催化降解  化学结构  染料废水  降解  废水处理
修稿时间:2001年6月25日

Study on Synthesis and Dye Wastewater Photo-catalytic Degradation of Iron-tetrasulfophthalocyanine
Wang Zaosheng Xu Yiming.Study on Synthesis and Dye Wastewater Photo-catalytic Degradation of Iron-tetrasulfophthalocyanine[J].Shanghai Environmental Science,2001,20(10):480-481.
Authors:Wang Zaosheng Xu Yiming
Abstract:Ironphthalocyanine and its sulfonated derivative were synthesized through the method of 1,2-Dicyanobenzene. Bleaching the dye Reactive Brilliant Red X-ZB by irradiation with light at A >320nm in an aqueoas solution of FePcSx species has been studied under various conditions. It was observed that the dye could be catalytic degraded effectively when it was irradiated in the iron-tetrasulfophthalocyanine and H2O2 solution. But the dye could not be degraded completely when in H2O2 solution only.
Keywords:Tetrasulfophthalocyanine Synthesis Photo-catalytic degradation Chemical structure  
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