Abstract: | The recycling of rubber from old tyres by batch hydrogenation has been performed using tubing bomb reactors. Important process variables like temperature, reaction time, initial hydrogen pressure and nature of gas used have been studied. In all the runs the maximum total conversion was achieved. Conversion products are comprised of oils and gases, being the asphaltene yield lower than 1% in all conditions tested. The most valuable conversion products, oils, have been systematically analysed by TLC-FID1 and the influence of the process variables in oils composition has been assessed. From the obtained results, it can be deduced that the conversion of rubber in oils is a fast thermal process, which is neither affected by initial pressure nor the nature of gas used. But on the other hand, the nature of obtained oils and gases is a function of process variables. |