Platin im Regenabfluß einer Straße

Using platinum based catalytic converters, platinum is emitted with the exhaust gases and deposited on the roads, and in their vicinity (sewage treatment plants, rivers), which increases the platinum concentrations in aquatic eco-systems. To evaluate the platinum discharge from roads, the platinum concentration was measured in rainwater from a road with a traffic fre quency of 16,000 automobiles per day. The platinum content of the samples varies strongly dependent upon the previous dry period, and the intensity and duration of the rainfall. Platinum was measured in 18 run-off samples from various rainfall events. The maximum platinum concentrations showed values up to 1.1. μg/l. The median value was 15 ng/l. Analysis of a sample from one rainfall events shows that platinum has a well defined firstflush effect, similar to that of particular bound lead and copper. The good correlation between platinum and coarse suspended matter, coarse particular lead and copper indicates that platinum in road run-offs is frequently found to be particular bound. Under the assumption that the road has been completely washed off, the platinum deposition can be estimated to be 14 ng/(m²d).