Relative humidity and temperature dependence of the ammonium nitrate dissociation constant |
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Institution: | 1. National and Kapodistrian University of Athens (NKUA), Division of Physics, Department of Environmental Physics and Meteorology, Build. Phys. V, University Campus, Zografou, 157 84 Athens, Greece;2. Bergische Universität Wuppertal (BUW), Faculty of Natural Sciences and Mathematics, Department of Chemistry, Laboratory for Physical Chemistry, 42097 Wuppertal, Germany;3. Karlsruhe Institute of Technology, Institute for Meteorology and Climate Research, Atmospheric Environmental Research (IMK-IFU), Kreuzeckbahnstr. 19, 82467 Garmisch-Partenkirchen, Germany |
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Abstract: | Expressions for predicting the temperature and relative humidity dependence of the NH4NO3 dissociation constant are derived from fundamental thermodynamic principles. The general trends predicted by the theory agree with the atmospheric data of Appel et al. (1979,1980), Pitts (1978,1979) and Tuazon et al. (1980). |
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