| 乳状液膜法处理煤制兰炭废水 |
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| 引用本文： | 刘涛,程迪,李鹏. 乳状液膜法处理煤制兰炭废水[J]. 化工环保, 2013, 33(3): 235-238 |
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| 作者姓名： | 刘涛 程迪 李鹏 |
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| 作者单位： | 中国中化集团公司，沈阳化工研究院环保室，辽宁，沈阳，110021 |
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| 摘 要： | 以磷酸三丁酯(TBP)为载体、煤油为膜溶剂、NaOH水溶液为内水相，采用乳状液膜法处理兰炭废水。实验结果表明:当TBP体积分数为4%、表面活性剂质量分数为4%、内水相NaOH质量分数为12%、油内比(乳状液的油相与内水相的体积比)为3∶2、乳水比为1∶5、萃取时间为15min时，废水中的酚类(以苯酚计)去除率达到85%以上，COD去除率达83%以上。
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| 关 键 词： | 兰炭 乳状液膜 磷酸三丁酯 萃取 废水处理[ |
| 收稿时间： | 2013-06-25 |
Treatment of Semi-coke Production Wastewater by Emulsion Liquid Membrane Process |
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| Liu Tao , Cheng Di , Li Peng. Treatment of Semi-coke Production Wastewater by Emulsion Liquid Membrane Process[J]. Environmental Protection of Chemical Industry, 2013, 33(3): 235-238 |
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| Authors: | Liu Tao Cheng Di Li Peng |
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| Affiliation: | Department of Environment Protection,Shenyang Research Institute of Chemical Industry,SINOCHEM,Shenyang Liaoning 110021,China |
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| Abstract: | The semi-coke production wastewater was treated by emulsion liquid membrane method using tributyl phosphate (TBP) as carrier,kerosene as membrane solvent,and NaOH solution as aqueous phase. The experimental results show that when the TBP volume fraction is 4%,the surfactant mass fraction is 4%,the mass concentration of NaOH in the internal phase is 12%,the volume ratio of oil to internal phase is 3;2,the volume ratio of emulsion liquid to wastewater is 1;5 and the extraction time is 15 min,the removal rats of phenols (calculated in phenol) and COD are above 85% and 83% respectively. |
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| Keywords: | semi-coke emulsion liquid membrane tributyl phosphate extraction wastewater treatment |
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