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Observations of N2O5 and NO3 at a suburban environment in Yangtze river delta in China: Estimating heterogeneous N2O5 uptake coefficients |
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| Authors: | Zhiyan Li Pinhua Xie Renzhi Hu Dan Wang Huawei Jin Hao Chen Chuan Lin Wenqing Liu |
| Institution: | Key laboratory of Environmental Optical and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Science, Hefei 230031, China;Department of Optoelectronic Engineering, School of Mathematics and Physics, Anhui University of Technology,Ma'an Shan 243032, China;Key laboratory of Environmental Optical and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Science, Hefei 230031, China;CAS Center for Excellence in Urban Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China;University of Chinese Academy of Sciences, Beijing 100049, China;Key laboratory of Environmental Optical and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Science, Hefei 230031, China;Department of Optoelectronic Engineering, School of Mathematics and Physics, Anhui University of Technology,Ma'an Shan 243032, China;College of Mechanical Engineering, Suzhou University of Science and Technology, Suzhou 215009, China |
| Abstract: | The nitrate radical (NO3) and dinitrogen pentoxide (N2O5) play an important role in the nocturnal atmosphere chemistry. Observations of NO3 radicals and N2O5 were performed in a semirural ground site at Tai'Zhou in polluted southern China using cavity ring down spectroscopy (CRDS) from 23 May to 15 June 2018. The observed NO3 and N2O5 concentrations were relatively low, with 1 min average value of 4.4 ± 2.2 and 26.0 ± 35.7 pptV, respectively. The N2O5 uptake coefficient was determined to be from 0.027 to 0.107 based on steady state lifetime method. Fast N2O5 hydrolysis was the largest contributor to the loss of NO3 and contributed to substantial nitrate formation, with an average value of 14.83 ± 6.01 µg/m3. Further analysis shows that the N2O5 heterogeneous reactions dominated the nocturnal NOx loss and the nocturnal NOx loss rate is 0.14 ± 0.02 over this region. |
| Keywords: | Corresponding author Cavity ring down spectroscopy 2 3 Uptake coefficient Nighttime chemistry |
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