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Solubility of toluene,benzene and TCE in high-microbial concentration systems
Institution:1. Équipe Verres et Céramiques (V&C), ISCR CNRS UMR 6226, Université de Rennes 1, Rennes, 35042, France;2. School of Engineering and Materials Science, Queen Mary University of London, London, E1 4NS, United Kingdom;3. Institut de Physique de Rennes, CNRS UMR 6251, Université de Rennes 1, Rennes, 35042, France;1. State Key Laboratory of Heavy Oil Processing, Beijing Key Lab of Oil & Gas Pollution Control, China University of Petroleum-Beijing, Beijing 102249, China;2. Department of Civil and Environmental Engineering, Rice University, Houston, TX 77005, USA;3. Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing 100085, China;4. Institute for Environmental Genomics, and Department of Microbiology and Plant Biology, University of Oklahoma, Norman, OK 73019, USA;5. State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China;6. Earth Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94270, USA;1. Department of Chemical Engineering, Federal University of Paraná (UFPR), Curitiba 82530-990, PR, Brazil;2. Department of Chemistry, Federal University of Paraná (UFPR), Curitiba 81531-990, PR, Brazil;1. CSIRO Materials Science and Engineering, PO Box 218, Lindfield, NSW 2070, Australia;2. CSIRO Computational Informatics, 65 Brockway Road, Floreat, WA 6014, Australia
Abstract:We report measurements of solubility limits for benzene, toluene, and TCE in systems that contain varying levels of biomass up to 0.13 g mL−1 for TCE and 0.25 g mL−1 for benzene and toluene. The solubility limit increased from 21 to 48 mM when biomass (in the form of yeast) was added to aqueous batch systems containing benzene. The toluene solubility limit increased from 4.9 to greater than 20 mM. For TCE, the solubility increased from 8 mM to more than 1000 mM. Solubility for TCE (trichloroethylene) was most heavily impacted by biomass levels, changing by two orders of magnitude as the microbial concentrations approach those in biofilms.
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