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Atmospheric gas and particle measurements at a rural northeastern U.S. site
Affiliation:1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China;2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China
Abstract:Ammonia, nitric acid, sulfur dioxide and particles in two size ranges were collected at a rural site in northeastern U.S. in January–March 1984. Ammonia was collected with an oxalic acid coated denuder, all other components were collected on filters. The concentrations of ammonia ranged between 0.0 and 0.5 ppbv, nitric acid: 0.1 and 2.3 ppbv and sulfur dioxide: 1 and 52 ppbv. Ammonium and sulfate in the fine particles were highly correlated, the regression line indicated that the most abundant compound was ammonium sulphate. The content of free hydronium ions in the fine particles was well below the ammonium content. No correlation between NH3 and NH+4, HNO3 and NO3 SO3 and SO−24 could be observed.
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