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电絮凝-超滤组合技术处理含铜废水
引用本文:赵凯,杨春风,孙境求,王云飞,李静,胡承志.电絮凝-超滤组合技术处理含铜废水[J].环境工程学报,2017,11(6):3352-3356.
作者姓名:赵凯  杨春风  孙境求  王云飞  李静  胡承志
作者单位:1. 中国科学院饮用水科学与技术重点实验室, 中国科学院生态环境研究中心, 北京 100085; 2. 河北工业大学土木与交通学院, 天津 300401; 3. 中国科学院大学, 北京 100049
基金项目:国家自然科学基金资助项目(51378490) 国家水体污染控制与治理科技重大专项(2015ZX07402003-3)
摘    要:采用电絮凝-超滤(electrocoagulation-ultrafiltration,EC-UF)组合技术对含铜废水中的铜离子进行了处理实验研究。讨论了电流密度、初始pH、初始铜浓度和初始电导率等因素对铜的去除效果和膜污染的影响,并分析了这些影响因素对EC-UF组合技术效率的作用机制。结果表明,在电流密度J=50 A·m-2、初始铜浓度C(Cu2+)≤40 mg·L-1、初始pH=4~8、初始电导率σ=2 mS·cm-1、电解时间20 min的条件下,废水中铜的去除率达到99.6%并有效的减缓了膜污染。本研究为EC-UF组合技术除铜的实践应用提供了科学依据。

关 键 词:电絮凝    超滤膜        膜污染
收稿时间:2016-06-17

Removal of copper from wastewater by hybrid electrocoagulation and ultrafiltration processes
ZHAO Kai,YANG Chunfeng,SUN Jingqiu,WANG Yunfei,LI Jing,HU Chengzhi.Removal of copper from wastewater by hybrid electrocoagulation and ultrafiltration processes[J].Techniques and Equipment for Environmental Pollution Control,2017,11(6):3352-3356.
Authors:ZHAO Kai  YANG Chunfeng  SUN Jingqiu  WANG Yunfei  LI Jing  HU Chengzhi
Institution:1. Key Laboratory of Drinking Water Science and Technology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; 2. School of Civil and Transportation, Hebei University of Technology, Tianjin 300401, China; 3. University of Chinese Academy of Sciences, Beijing 100049, China
Abstract:This study investigated the performance of copper removal from synthetic model wastewater by hybrid electrocoagulation and ultrafiltration processes (EC-UF).The effects of current density, initial pH, initial copper concentration, solution conductivity, and other factors on the removal of copper and membrane-fouling were studied, and the influence mechanism of these factors on EC-UF efficiency was analyzed.The copper removal rate was found to reach 99.6%, and membrane-fouling was effectively alleviated at a current density of 50 A·m-2, initial C(Cu2+) ≤ 40 mg·L-1, initial pH of 4 to 8, solution conductivity of 2 mS·cm-1, and electrolysis time of 20 min.These results provide a scientific basis for further research on EC-UF removal of copper ions.
Keywords:electrocoagulation  ultrafiltration  copper  membrane fouling
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