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低温等离子体净化尾气中的颗粒相多环芳烃
引用本文:马朝臣, 高建兵, 邢世凯, 杨文芳. 低温等离子体净化尾气中的颗粒相多环芳烃[J]. 环境工程学报, 2017, 11(2): 988-992. doi: 10.12030/j.cjee.201510051
作者姓名:马朝臣  高建兵  邢世凯  杨文芳
作者单位:1.北京理工大学机械与车辆学院, 北京 100081; 2.河北师范大学职业技术学院, 石家庄 050024; 3.北京汽车动力总成有限公司, 北京 101108
基金项目:河北省科技计划项目资助(15273703D)
摘    要:利用低温等离子体(NTP)净化车用柴油机尾气中的颗粒相多环芳烃(PAHs),基于电晕放电的原理,设计了NTP发生装置。使用色谱质谱联用仪分析经过NTP净化前后柴油机尾气中颗粒相多环芳烃的含量,观察NTP对颗粒相多环芳烃的净化效果。结果表明,颗粒相小分子量PAHs除菲、蒽外,其他4种多环芳烃的含量显著增加,其中萘、苊变化率达1 130.4%和758.57%;大分子量PAHs除苯并(ghi)芘外,多环芳烃的含量降低达80%以上;NTP对柴油机尾气中颗粒相多环芳烃含量及毒性当量的净化率分别达58.4%和82.8%。

关 键 词:柴油机   低温等离子体   多环芳烃   毒性当量
收稿时间:2015-11-13

Cleaning particle-phase polycyclic aromatic hydrocarbons of exhaust using non-thermal plasma technology
MA Chaochen, GAO Jianbing, XING Shikai, YANG Wenfang. Cleaning particle-phase polycyclic aromatic hydrocarbons of exhaust using non-thermal plasma technology[J]. Chinese Journal of Environmental Engineering, 2017, 11(2): 988-992. doi: 10.12030/j.cjee.201510051
Authors:MA Chaochen  GAO Jianbing  XING Shikai  YANG Wenfang
Affiliation:1.School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081, China; 2.School of Vocational and Technical, Hebei Normal University, Shijiazhuang 050024, China; 3.Automotive Powertrain Co., Ltd., Beijing 101108, China
Abstract:Particle-phase polycyclic aromatic hydrocarbon (PAH) emissions from a diesel engine were purified with non-thermal plasma (NTP) technology. The NTP reactor was designed based on a corona discharge. PAHs both with and without NTP were quantified with gas-chromatography mass spectrometry (GC-MS). The levels of PAHs were analyzed based on GC-MS results. The results showed that the content of PAHs increased greatly for light particle-phase PAHs except for Phe and AnT. The increases in the percentage of NaP and AcPy were 1130.4% and 758.57%, respectively. The decrease in heavy PAHs exceeded 80%, except for BghiP. The content and BaPeq of the PAHs with and without NTP dropped to 58.4% and 82.8%, respectively.
Keywords:diesel engine  non-thermal plasma  polycyclic aromatic hydrocarbons  toxicity equivalency quantity
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