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湿法并联氧化的脱硝机理
引用本文:张蕾, 马振华, 张磊, 沙响玲, 何会彬, 陈吉浩, 林琪. 湿法并联氧化的脱硝机理[J]. 环境工程学报, 2017, 11(7): 4190-4195. doi: 10.12030/j.cjee.201605004
作者姓名:张蕾  马振华  张磊  沙响玲  何会彬  陈吉浩  林琪
作者单位:1.西安科技大学地质与环境学院, 西安 710054; 2.中国重型机械研究院股份公司, 西安 710032; 3.河北省保定市中勘冶金勘察设计研究院有限责任公司, 保定 071069
基金项目:陕西省科技统筹创新工程计划项目(2012KTZB03-01-02) 国土资源部煤炭资源勘察与综合利用重点实验室开放课题资助项目(KF2015-1)
摘    要:采取模拟烟气通过含有强氧化性的溶液(H2O2和KMnO4)在鼓泡反应装置中进行单一的实验,研究吸收剂的温度和浓度对脱硝效率的影响,得出其最优脱硝条件,选取3种氧化剂的最优值进行并联实验,并分析其脱硝机理得出并联条件下的最优脱硝试剂。结果表明,H2O2的最优脱硝条件为:温度为60 ℃,浓度为0.5%,其达到稳定时的脱硝效率为58%;KMnO4的最优脱硝条件为温度为40 ℃,浓度为0.2%,达到稳定时的脱硝效率为77%;并联条件下最优脱硝试剂为KMnO4和NaClO2,其脱硝效率为83%。

关 键 词:模拟烟气   鼓泡反应装置   氧化脱硝   湿法   并联
收稿时间:2016-06-27

Mechanism of wet oxidation denitration in parallel
ZHANG Lei, MA Zhenhua, ZHANG Lei, SHA Xiangling, HE Huibin, CHEN Jihao, LIN Qi. Mechanism of wet oxidation denitration in parallel[J]. Chinese Journal of Environmental Engineering, 2017, 11(7): 4190-4195. doi: 10.12030/j.cjee.201605004
Authors:ZHANG Lei  MA Zhenhua  ZHANG Lei  SHA Xiangling  HE Huibin  CHEN Jihao  LIN Qi
Affiliation:1.College of Geology and Environment, Xi'an University of Science and Technology, Xi'an 710600, China; 2.China National Heavy Machinery Research Institute Co. Ltd., Xi'an 710032, China; 3.Baoding, Hebei Province Survey and Design Institute of Metallurgical Survey Limited Liability Company, Baoding 071069, China
Abstract:Take simulated flue gas through the solution (H2O2, KMnO4) containing strong oxidizing conducting impact single experiment, study absorbent temperature and concentration on denitrification efficiency in bubbling reaction apparatus, obtain optimal denitrification conditions, and select the optimal value three-oxidants pairwise parallel experiment analysis denitrification mechanism of denitration reagents obtained under optimal parallel conditions. The experimental results show that:the optimal Denitrification Conditions of H2O2 are as follows, the temperature is 60℃, the concentration is 0.5%, and the denitrification efficiency is 58%;The optimal Denitrification temperature and concentration of KMnO4 were 40℃, 0.2%, and the denitrification efficiency was 77%;and the denitrification efficiency was as follows, KMnO4 and NaClO2, the denitrification efficiency was 83%.
Keywords:simulated flue gas  bubbling reaction apparatus  oxidation denitrification  wet  parallel connection
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