Effect of Ca(II), Fe(II), and Fe(III) on Cu(II) adsorption by a polyvinylidene fluoride-based chelating membrane from Cu(II)–EDTA complex solution |
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Authors: | Laizhou Song Xiuli Wang Dandan Yun Feifei Yang Jun He Ruifang Zhao |
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Institution: | Department of Environmental Science and Engineering, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, China |
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Abstract: | A polyvinylidene fluoride-based membrane bearing the diethylenetriaminepentaacetic acid chelating group was employed to recover Cu(II) from the Cu(II)-ethylenediaminetetraacetic acid complex aqueous solution. Effects of Ca(II), Fe(II), and Fe(III) on Cu(II) uptake were investigated by static batch adsorption tests and dynamic adsorption filtration. Isotherms, kinetics, and breakthrough curves of Cu(II) uptakes in the presence of the three cations at concentrations of 1 mmol L?1 were elucidated. The three cations showed a positive effect on the Cu(II) uptake; the stimulative roles were in the order of Fe(III) > Fe(II) > Ca(II). They did not alter the adsorption behavior of the membrane; adsorption isotherms and kinetics could be described by Langmuir and Lagergren second-order models, and Cu(II) adsorption was a spontaneous and exothermic process. The presence of Ca(II), Fe(II), and Fe(III) increased the sorption capacity of the membrane stack by 1.3, 1.9, and 3 times. Breakthrough time and the exhaustion time of membrane stacks were also extended. |
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Keywords: | Polyvinylidene fluoride-based chelating membrane diethylenetriaminepentaacetic acid group adsorption Cu(II)–EDTA complex coexisting cation |
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