Influence of bromine on metal volatilization in waste combustion |
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Authors: | Jürgen Vehlow Frank E Mark |
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Institution: | (1) Forschungszentrum Karlsruhe GmbH, Institute for Technical Chemistry, Division of Thermal Waste Treatment, POB 3640, D-76133 Karlsruhe, Germany Tel. +49-7247-82-4372; Fax +49-7247-82-4373 e-mail: vehlow@itc-tab.fzk.de, DE;(2) Dow Europe, Bachtobelstr. 4, CH-8810 Horgen, Germany, DE |
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Abstract: | Co-combustion tests of municipal solid waste and bromine-containing waste plastics have been performed in the TAMARA test
incinerator in order to investigate the fate of bromine in waste combustion. HBr is the main bromine combustion product. Approximately
50% of the bromine inventory stays in the grate ashes, which is much more than is found for chlorine. The percentage of bromine
transferred into the fly ash also exceeds that of chlorine. There is a strong indication that bromine has a promoting effect
upon the volatility of most of the heavy metals that are typically mobilized by chlorine.
Received: February 2, 2000 / Accepted: March 3, 2000 |
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Keywords: | Waste combustion Bromine Chlorine Flame-retarded plastics Metal volatilization |
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