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碱激发胶凝材料及其固化Pb^2+的试验研究
引用本文:郑娟荣,胡洁.碱激发胶凝材料及其固化Pb^2+的试验研究[J].环境污染治理技术与设备,2009(4):733-738.
作者姓名:郑娟荣  胡洁
作者单位:郑州大学土木工程学院,郑州450002
基金项目:国家自然科学基金资助项目(50572096)
摘    要:对碱激胶凝材料(碱-偏高岭土、碱-矿渣和碱-粉煤灰)与水-水泥体系固化Ph^2+进行了试验研究,其中水-水泥体系为对比样。结果表明:对于相同稠度的碱激发胶凝材料,即使Pb^2+含量达到2.4%,除了碱-粉煤灰的抗压强度略低外,其他都达到30MPa以上,满足填埋或做建筑基材的使用要求;与水泥相比,碱激发胶凝材料能显著降低重金属离子(Ph^2+)浸出浓度,其规律性与其NH4交换容量大小的规律性一致,与其固化体的抗压强度的大小没有相关性。

关 键 词:碱激胶凝材料  固化  重金属离子(Pb2+)  NH4+交换容量  抗压强度

Test study on alkali-activated cementing materials and their solidification of Pb^2+
Zheng Juanrong Hu Jie.Test study on alkali-activated cementing materials and their solidification of Pb^2+[J].Techniques and Equipment for Environmental Pollution Control,2009(4):733-738.
Authors:Zheng Juanrong Hu Jie
Institution:Zheng Juanrong Hu Jie (College of Civil Engineering, Zhengzhou University, Zhengzhou 450002)
Abstract:The solidification of heavy metal ( Pb^2+) by alkali-activated cementing materials(alkali-metakaolinite,alkali-slag, alkali-fly ash) and water-cement was studied, in which water-cement acted as a control sample. The results showed that the compressive strengths of hardened alkali-activated cementing material pastes with the same consistency were above 30 MPa except alkali-fly ash even when Pb^2+ content rose to 2.40% ,which met the demand of base building material or landfill; alkali-activated cementing remarkably decreased Pb^2+ leaching concentration of the solidification bodies in the light of cement, the decreasing law were identical with law of capacity of NH4^+ ion exchange of the solidification bodies but were not related to the compressive strengths of solidification bodies materials.
Keywords:alkali-activated cementing materials  solidification  heavy metal (Pb^2+ )  capacity of NH4^+ ion exchange  compressive strengths
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