Assessment of intrinsic bioremediation of a coal-tar-affected aquifer using Two-dimensional reactive transport and Biogeochemical mass balance approaches. |
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Authors: | Shane W Rogers Say Kee Ong Greg A Stenback Johanshir Golchin Bruce H Kjartanson |
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Affiliation: | U.S. Environmental Protection Agency's National Risk Management Research Laboratory, Cincinnati, Ohio, USA. |
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Abstract: | Expedited site characterization and groundwater monitoring using direct-push technology and conventional monitoring wells were conducted at a former manufactured gas plant site. Biogeochemical data and heterotrophic plate counts support the presence of microbially mediated remediation. By superimposing solutions of a two-dimensional reactive transport analytical model, first-order degradation rate coefficients ((day-1) ) of various compounds for the dissolved-phase plume were estimated (i.e., benzene [0.0084], naphthalene [0.0058], and acenaphthene [0.0011]). The total mass transformed by aerobic respiration, nitrate reduction, and sulfate reduction around the free-phase coal-tar dense-nonaqueous-phase-liquid region and in the plume was estimated to be approximately 4.5 kg/y using a biogeochemical mass-balance approach. The total mass transformed using the degradation rate coefficients was estimated to be approximately 3.6 kg/y. Results showed that a simple two-dimensional analytical model and a biochemical mass balance with geochemical data from expedited site characterization can be useful for rapid estimation of mass-transformation rates. |
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