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单级和两级串联臭氧-生物活性炭深度处理垃圾渗滤液的比较研究
引用本文:杜安静,范举红,刘锐,邱松凯,文晓刚,陈吕军. 单级和两级串联臭氧-生物活性炭深度处理垃圾渗滤液的比较研究[J]. 环境科学, 2015, 36(11): 4154-4160
作者姓名:杜安静  范举红  刘锐  邱松凯  文晓刚  陈吕军
作者单位:浙江清华长三角研究院生态环境研究所, 浙江省水质科学与技术重点实验室, 嘉兴 314006;上海师范大学生命与环境科学学院, 上海 200234;浙江清华长三角研究院生态环境研究所, 浙江省水质科学与技术重点实验室, 嘉兴 314006;浙江清华长三角研究院生态环境研究所, 浙江省水质科学与技术重点实验室, 嘉兴 314006;浙江清华长三角研究院生态环境研究所, 浙江省水质科学与技术重点实验室, 嘉兴 314006;嘉兴学院南湖学院, 嘉兴 314001;浙江清华长三角研究院生态环境研究所, 浙江省水质科学与技术重点实验室, 嘉兴 314006;清华大学环境学院, 北京 100084
基金项目:浙江省重大科技专项(2012C03002-1); 浙江省环境保护厅科技计划项目(2013B005); 福建省产业支撑科技重大项目(合作)(201211005); 嘉兴市科技计划项目(SQ2014010433)
摘    要:使用单级和两级串联臭氧-生物活性炭(O3-BAC)处理垃圾焚烧渗滤液的二级生物处理尾水,比较研究了污染物去除效果.结果表明,臭氧投加量为200 mg·L-1时,两级串联O3-BAC对COD、UV254和色度的去除率分别为75.9%±2.1%、78.8%±2.9%和96.8%±0.9%,处理出水COD基本保持在100 mg·L-1以下,色度低于40倍,满足GB 16889-2008排放要求;而单级O3-BAC对COD、UV254和色度的去除率分别为68.2%±1.3%、69.7%±0.5%和92.5%±1.1%,处理出水COD和色度分别为150 mg·L-1和60倍,不能达到排放要求.单级O3-BAC在290 mg·L-1臭氧投加量下,才能达到两级串联O3-BAC在200mg·L-1臭氧投加量下的污染物去除效果.此外,两级串联O3-BAC在臭氧投加量200 mg·L-1时的总磷去除率为63.5%±4.4%,出水总磷浓度稳定在1 mg·L-1以下,直接满足GB 16889-2008排放要求.

关 键 词:垃圾渗滤液  臭氧氧化  生物活性炭  比较研究  去除效果
收稿时间:2015-03-16
修稿时间:2015-06-12

Advanced Treatment of Incineration Leachate with O3-BAC and Double O3-BAC
DU An-jing,FAN Ju-hong,LIU Rui,QIU Song-kai,WEN Xiao-gang and CHEN L,#;-jun. Advanced Treatment of Incineration Leachate with O3-BAC and Double O3-BAC[J]. Chinese Journal of Environmental Science, 2015, 36(11): 4154-4160
Authors:DU An-jing,FAN Ju-hong,LIU Rui,QIU Song-kai,WEN Xiao-gang  CHEN L&#  -jun
Affiliation:Zhejiang Provincial Key Laboratory for Water Science and Technology, Department of Environment, Yangtze Delta Region Institute of Tsinghua University in Zhejiang, Jiaxing 314006, China;College of Life and Environmental Science, Shanghai Normal University, Shanghai 200234, China;Zhejiang Provincial Key Laboratory for Water Science and Technology, Department of Environment, Yangtze Delta Region Institute of Tsinghua University in Zhejiang, Jiaxing 314006, China;Zhejiang Provincial Key Laboratory for Water Science and Technology, Department of Environment, Yangtze Delta Region Institute of Tsinghua University in Zhejiang, Jiaxing 314006, China;Zhejiang Provincial Key Laboratory for Water Science and Technology, Department of Environment, Yangtze Delta Region Institute of Tsinghua University in Zhejiang, Jiaxing 314006, China;Nanhu College, Jiaxing University, Jiaxing 314001, China;Zhejiang Provincial Key Laboratory for Water Science and Technology, Department of Environment, Yangtze Delta Region Institute of Tsinghua University in Zhejiang, Jiaxing 314006, China;School of Environment, Tsinghua University, Beijing 100084, China
Abstract:Ozone-biological activated carbon (O3-BAC) process and double O3-BAC process were respectively used for advanced treatment of the biologically treated effluent of incineration leachate, and their pollutant removal performances were compared. The results showed that the double O3-BAC removed 75.9%±2.1% of chemical oxygen demand (COD), 78.8%±2.9% of UV254 and 96.8%±0.9% of color at ozone dosage of 200 mg ·L-1. The treated effluent was with COD of below 100 mg ·L-1 and color of below 40 times, meeting the emission requirements of GB 16889-2008. At the same ozone dosage, however, the O3-BAC removed 68.2%±1.3% of COD, 69.7%±0.5% of UV254 and 92.5%±1.1% of color. The treated effluent was with COD of around 150 mg ·L-1 and color of about 60 times, failing to meet the emission requirements. Namely, ozone of 290 mg ·L-1 was required by O3-BAC in order to achieve similar pollutant removals as those in double O3-BAC at O3 dosage of 200 mg ·L-1. In double O3-BAC at ozone dosage of 200 mg ·L-1, total phosphorus was removed by 63.5%±4.4%, and the phosphorus concentration in the effluent was remained 1 mg ·L-1 or less, directly meeting the emission requirement of GB 16889-2008.
Keywords:landfill leachate  ozonation  biological activated carbon  comparative study  removal efficiency
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