Kinetic modelling of the pyrolysis of Miscanthus × Giganteus from the thermogravimetric analysis of its fractionated components |
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Authors: | Salvatore Collura Bruno Azambre Jean-Victor Weber |
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Institution: | (1) Laboratoire de Chimie et Applications (EA 3471), Université de Metz- Rue Victor Demange, 57500 Saint-Avold, France |
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Abstract: | In this paper the thermal behaviour of Miscanthus × Giganteus (M×G) is studied by thermogravimetric analysis. In order to
characterise the thermal behaviour of its cellulose, hemicellulose and lignin, the raw M×G material was treated sequentially
by water, H2SO4 and KOH. The global kinetic parameters for each component were determined by subsequent modelling of the TG data with the
Ozawa-Flynn-Wall method and multivariate non-linear regression. It is found that the global pyrolysis of M×G can be satisfactorily
described using a six steps-kinetic scheme. The analytical method proposed here can be probably extended without too many
efforts to other biomass products.
An erratum to this article can be found at |
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Keywords: | Miscanthus Thermogravimetry Kinetic parameters Ozawa-Flynn-Wall method Chemical fractionation |
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