Bisolute Equilibrium Studies for the Sorption of Basic Dyes on a GAC from Almond Shells: A Nonlinear Approach |
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Authors: | J N Yesuf B A DeVantier L R Chevalier |
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Institution: | (1) Dept. of Civil and Environmental Engineering, Southern Illinois University Carbondale, Mail Code 6603, Carbondale, IL 62901, USA |
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Abstract: | Aqueous phase adsorption of three textile dyes onto a granular activated carbon produced from acid activation of almond shells
is presented. Primarily, the sorption of three basic dyes, methylene blue, rhodamine b, and malachite green oxalate were studied.
Four models, the Freundlich, the Langmuir, the Redlich-Peterson, and the Toth isotherms were compared for their quality of
fit to the single-solute sorption data. Next, sorption of the three likely binary systems was examined. Four bi-solute models,
the extended Langmuir with and without an interaction term, the extended Redlich-Peterson with an interaction term, and the
empirical extended Freundlich model were used to predict sorption in the binary systems. Nonlinearly determined constants
of the corresponding single-solute isotherms were used in the binary models to compare with experimental binary sorption data.
For the single-solute system, the three-parameter models of the Redlich-Peterson and the Toth isotherms outperformed the Langmuir
and Freundlich models. The empirical extended Freundlich model produced the closest comparison to the binary data in each
system. In general, the nonlinear method provided a simple and computationally effective technique of producing optimal fitting
parameters for the bi-solute sorption models. |
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Keywords: | Isotherms Sorption Textile dyes Bisolute Activated carbon Nonlinear |
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