Application of a purge and trap TDS-GC/MS procedure for the determination of emissions from flame retarded polymers |
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| Authors: | Wolf M Riess M Heitmann D Schreiner M Thoma H Vierle O van Eldik R |
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| Affiliation: | Institut für Anorganische Chemie, Universit?t Erlangen-Nürnberg, Erlangen, Germany. |
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| Abstract: | Emissions of volatile organic compounds (VOCs) from different thermoplastic polymers used in electrotechnical applications were investigated using a purge and trap procedure that involved adsorption on Tenax GR. Results were compared to those for an operating TV set monitored in a test chamber. The analyses were in both cases carried out using thermodesorption gas chromatography with mass spectrometric detection (TDS-GC/MS). Substances identified were monomers, volatile additives, or related compounds. Special attention was given to the detection of halogenated compounds. Their origin was studied using reference samples and synthetic standards. |
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