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ESA/AMPS共聚物与磁场的协同阻垢作用
引用本文:刘展,刘振法,张利辉,王昕. ESA/AMPS共聚物与磁场的协同阻垢作用[J]. 环境污染治理技术与设备, 2013, 0(10): 3979-3984
作者姓名:刘展  刘振法  张利辉  王昕
作者单位:[1]河北工业大学化工学院,天津300130 [2]河北省工业节水工程技术研究中心,石家庄050081 [3]河北省科学院能源研究所,石家庄050081
基金项目:河北省自然科学基金资助项目(B2011302001,B2010001558)
摘    要:采用静态阻垢试验方法研究了磁场与ESA/AMPS共聚物共同作用时的协同阻垢性能。结果表明,磁场与ESA/AMPS共聚物对碳酸钙和磷酸钙有协同阻垢作用,当磁化水流量为120L/h、磁场强度为0.7T、磁化时间为40min、ESA/AMPS共聚物用量为3mg/L时,ESA/AMPS共聚物与磁场对CaCO3的协同阻垢率比单独使用ESA/AMPS共聚物时提高了12%;在其他条件不变,而ESA/AMPS共聚物用量为14mg/L时,磁场与ESA/AMPS共聚物对Ca3(PO4)2的协同阻垢率比单独使用ESA/AMPS共聚物时提高42.4%。利用扫描电镜(SEM)和x-射线衍射仪(XRD)对CaCO,垢样进行了观察,发现ESA/AMPS共聚物对垢样晶型产生扭曲作用,而磁场与ESA/AMPS共聚物协同作用时的垢样晶型没有太大改变。

关 键 词:ESA  AMPS共聚物  磁场  阻垢率

Synergistic scale inhibition of both ESA/AMPS copolymer and magnetic field
Liu Zhan,Liu Zhenfa,Zhang Lihui,Wang Xin. Synergistic scale inhibition of both ESA/AMPS copolymer and magnetic field[J]. Techniques and Equipment for Environmental Pollution Control, 2013, 0(10): 3979-3984
Authors:Liu Zhan  Liu Zhenfa  Zhang Lihui  Wang Xin
Affiliation:1. School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China 2. Hebei Engineering Research Center for Water Saving in Industry, Shijiazhuang Hebei 050081, China; 3. Institute of Energy Sources, Hebei Academy of Science, Shijiazhuang Hebei 050081, China)
Abstract:The scale inhibition performances of both magnetic field and ESA/AMPS eopolymer were inves- tigated by using a static scale inhibition experiment, and the result showed that there was a synergistic scale inhi- bition effect between magnetic field and ESA/AMPS eopolymer. The scale inhibition rate of both magnetic field and ESA/AMPS copolymer on CaCO3increased by 12% as compared with that of ESA/AMPS eopolymer alone under the conditions of water flow of 120 L/h, magnetic field intensity of 0.7 T, magnetic treatment time of 40 min and the ESA/AMPS copolymer dosage of 3 mg/L. And the synergistic scale inhibition rate of both magnetic field and ESA/AMPS copolymer on Ca3 ( PO4 ) z increased by 42.4% as compared with that of ESA/AMPS copol- ymer alone under the same conditions except ESA/AMPS copolymer dosage of 14 mg/L. In addition, SEM and XRD characteristic results showed that ESA/AMPS copolymer could split and distort the crystal form of the re- sultant CaCO3 deposit samples while the synergism of both magnetic field and ESA/AMPS copolymer could not change the crystal form of the CaCO3deposit samples further.
Keywords:ESA/AMPS copolymer  magnetic field  scale inhibition rate
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