| Steady-state kinetics and osillation phenomena for complete oxidation of benzene over Pt/Al_2O_3 catalyst |
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| 作者姓名： | Yu Qiquan Jin Yun and Shi Fajun |
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| 作者单位： | Yu Qiquan，Jin Yun and Shi FajunDepartment of Chemistry，Peking University，Beijing 100871，China. |
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| 基金项目： | Supported by the National Sciences Fundation of China. |
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| 摘 要： | The steady-state kinetics for complete oxidation of benzene over has been investigated by the external recycling reactor. The kinetics equation was described by the L-H model of adsorption of benzene and oxygen with the inhibition of carbon dioxide. The parameters of the kinetics model were estimated by the method of orthogonal design. The heats of adsorption of benzene, oxygen and carbon dioxide were determined by the method of gas-adsorption chromatography. The details of oscillations of complete oxidation of benzene were investigated.
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Steady-state kinetics and osillation phenomena for complete oxidation of benzene over Pt/Al_2O_3 catalyst |
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| Yu Qiquan,Jin Yun and Shi Fajun.Steady-state kinetics and osillation phenomena for complete oxidation of benzene over Pt/Al_2O_3 catalyst[J].Journal of Environmental Sciences,1990(2). |
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| Authors: | Yu Qiquan Jin Yun and Shi Fajun |
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| Institution: | Yu Qiquan,Jin Yun and Shi FajunDepartment of Chemistry,Peking University,Beijing 100871,China. |
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| Abstract: | The steady-state kinetics for complete oxidation of benzene over has been investigated by the external recycling reactor. The kinetics equation was described by the L-H model of adsorption of benzene and oxygen with the inhibition of carbon dioxide. The parameters of the kinetics model were estimated by the method of orthogonal design. The heats of adsorption of benzene, oxygen and carbon dioxide were determined by the method of gas-adsorption chromatography. The details of oscillations of complete oxidation of benzene were investigated. |
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| Keywords: | steady-state kinetics complete oxidation benzene Pt/Al2O3 |
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