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Safety analysis of CSTR towards changes in operating conditions
Institution:1. Research Center for Compact Chemical System, National Institute of Advanced Industrial Science and Technology (AIST), 4-2-1 Nigatake, Miyagino, Sendai 983-8551, Japan;2. JST, PRESTO, 4-2-1 Nigatake, Miyagino, Sendai 983-8551, Japan;3. Department of Chemistry and Bioengineering, Faculty of Engineering, Iwate University, Ueda 4-3-5, Morioka 020-8551, Japan;1. Technische Universität Berlin, Process Dynamics and Operations Group, Sekr. KWT 9, Straße des 17. Juni 135, Berlin 10623, Germany
Abstract:Exothermic reactions are the most interesting systems for safety analysis because of their potential safety problems and the possibility of exotic behavior such as multiple steady states. A sensitivity analysis of an exothermic reaction involving the hydrolysis of propylene oxide to propylene glycol in a CSTR with jacket cooling is presented here. The objective of this article is to determine how multiple steady states might arise. A comparison of the static and continuation method of the identification of multiple steady states and their stability is presented. Finally, the implications of safety analysis for operation and control of reactors with multiple steady states are discussed.
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