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DETERMINATION OF ORGANIC PARAMETERS IN WASTE AND LEACHATES FROM THE HAZARDOUS WASTE LANDFILL OF RAINDORF; GERMANY
Institution:1. Research and Development Centre of Hazardous Waste, Schwabach, P.O. Box 1469, D-91104, Germany;2. Association for the Treatment and Disposal of Hazardous Waste in Central Franconia (ZVSMM), Schwabach, P.O. Box 2240, D-91124, Germany;1. State Key Lab of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China;2. School of Materials Science and Engineering, Harbin Institute of Technology (Shenzhen), Shenzhen 518055, China;1. Department of Chemical Engineering, University of Johannesburg, Johannesburg 2028, South Africa;2. Department of Mechanical Engineering, University of Johannesburg, Johannesburg 2028, South Africa;3. Department of Chemical Engineering, Vaal University of Technology, Private Bag ×021-Vanderbijilpark 1911, Andries Potgieter Blvd, South Africa;4. Department of Applied Chemistry, University of Johannesburg, Johannesburg 2028, South Africa;5. UN Environment in South Africa, Regional Office for Southern Africa, 351 Francis Baard Street, P.O. BOX 6541, Pretoria, South Africa;1. School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing, 100083, China;2. Beijing Key Laboratory of Resource-oriented Treatment of Industrial Pollutants, Beijing, 100083, China;3. Beijing Agro-Biotechnology Research Center, Beijing Academy of Agriculture and Forestry Sciences, Beijing, 100097, China
Abstract:Extensive investigations of leachates and solid waste samples for organic sum parameters and environmentally relevant organic compounds were carried out at the hazardous waste landfill of Raindorf, which is operated in accordance with German Technical Instructions on Waste (TI Waste). The measurements showed that the majority of the waste samples contained only minor amounts of phenols, highly volatile chlorinated organic compounds (VCHC), benzene, toluene, ethylbenzene and xylene (BTEX), polychlorinated biphenyls (PCB) and polycyclic aromatic hydrocarbons (PAH). The concentrations ranged from less than 100μg/kg?1up to 1000μg/kg?1of dry substance. Only hydrocarbons were detected in higher concentrations (mg to g kg?1of dry substance). In most leachate and gas samples taken at the landfill, the concentrations of the abovementioned parameters were close to or even below the detection limit. The measurement of organic single compounds underlined the usefulness of the sum parameters, adsorbable organic halogen compounds and phenol index, for the estimation of the total amount of these substances. A comparison of organic sum parameter concentrations measured in leachates from landfills of differing ages indicates that the application of TI Waste leads to a reduction of the organic load in the leachate.
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