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大气VOCs在线监测系统测量准确性分析
引用本文:王东方,聂剑文,欧阳鸿. 大气VOCs在线监测系统测量准确性分析[J]. 环境监控与预警, 2022, 14(1): 49-52. DOI: 10.3969/j.issn.1674-6732.2022.01.009
作者姓名:王东方  聂剑文  欧阳鸿
作者单位:上海建科环境技术有限公司,上海201108;上海老港固废综合开发有限公司,上海201302
基金项目:上海市科技攻关基金资助项目(20dz1204009);上海城投科技创新计划基金资助项目(CTKY-ZDXM-2019-019)
摘    要:基于在线气相色谱-氢火焰离子检测/质谱(GC-FID/MS)方法,在线测量116种大气挥发性有机物的性能指标(线性关系、检出限、精密度、正确度、期间正确度和期间精密度).基于在线监测系统连续7d的实际运行情况,定量评估116种有机物在实际长期运行中测量的准确性和可靠性.结果 表明,116种组分中,109种组分的线性相关...

关 键 词:大气  挥发性有机物  气相色谱-氢火焰离子检测/质谱  在线监测  准确性
收稿时间:2021-07-19
修稿时间:2021-08-04

Accuracy Analysis of VOCs in Air Online Monitoring
WANG Dong-fang,NIE Jian-wen,OUYANG Hong. Accuracy Analysis of VOCs in Air Online Monitoring[J]. Environmental Monitoring and Forewarning, 2022, 14(1): 49-52. DOI: 10.3969/j.issn.1674-6732.2022.01.009
Authors:WANG Dong-fang  NIE Jian-wen  OUYANG Hong
Affiliation:(Shanghai Jianke Enviromental Technology Co.Ltd.,Shanghai 201108,China;Shanghai Laogang Solid Waste Comprehensive Development Co.Ltd.,Shanghai 201302,China)
Abstract:Based on online GC-FID/MS method,the performance indexes of 116 atmospheric VOCs were analyzed including linearity,detection limit,precision,accuracy,period accuracy and period precision.The accuracy of 116 volatile organic compounds measured by GC-FID/MS was systematically analyzed.The measurement accuracy and reliability of 116 VOCs were quantitatively evaluated based on online operation for 7 consecutive days.The results showed that:among 116 species,the linear correlation coefficient(R)of 109 species was≥0.98;the minimum detection limit of the 113 species was<0.15 nmol/mol;the accuracy of the 103 species was within±15%,and the precision of all species was within 15%.
Keywords:Air   VOCs  GC FID/MS  Online monitoring   Accuracy
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