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羟基磷灰石对棕壤和红壤铜吸附的影响
引用本文:宋正国,唐世荣,丁永祯,居学海.羟基磷灰石对棕壤和红壤铜吸附的影响[J].生态环境,2011,20(1):164-168.
作者姓名:宋正国  唐世荣  丁永祯  居学海
作者单位:农业部环境保护科研监测所生态毒理与环境修复研究中心//农业部产地环境与农产品安全重点开放实验室//天津市农业环境与农产品安全重点实验室,天津,300191
基金项目:国家自然科学基金,天津市应用基础及前沿技术研究计划
摘    要:采用等温平衡法,观测了羟基磷灰石对红壤、棕壤铜吸附量的影响,并应用Freundlich方程Cs=KfCen分析了土壤铜的吸附特征。结果表明,棕壤对铜的吸附能力明显高于红壤。以n(磷)∶n(铜)=1∶1向棕壤与红壤中施用羟基磷灰石,会增加两种土壤对铜的吸附量。其中,羟基磷灰石影响红壤对铜吸附能力明显高于棕壤。增加羟基磷灰石的施用量,会增加红壤与棕壤对铜的吸附量,提高土壤铜的吸附能力。高量羟基磷灰石n(磷)∶n(铜)=4∶1]的作用效果最为明显;与对照相比,铜的吸附量分别增加62.1%和28.4%。据此推测,在铜污染红壤或棕壤上,可以选用羟基磷灰石作为磷肥的肥源。

关 键 词:羟基磷灰石    棕壤  红壤  吸附  分配系数

Effect of hydroxyapatite on copper sorption in brown earth and red soil
SONG Zhengguo,TANG Shirong,DING Yongzhen,JU Xuehai.Effect of hydroxyapatite on copper sorption in brown earth and red soil[J].Ecology and Environmnet,2011,20(1):164-168.
Authors:SONG Zhengguo  TANG Shirong  DING Yongzhen  JU Xuehai
Institution:SONG Zhengguo,TANG Shirong*,DING Yongzhen,JU Xuehai Institute of Environmental Protection,Ministry of Agriculture of China//Key Laboratory of Production Environment and Agro-Product Safety,Ministry of Agriculture of China//Key Laboratory of Agricultural Environment and Agro-Product Safety,Tianjin 300191,China
Abstract:The present paper uses the isothermal equilibrium theory to investigate the effect of hydroxyapatite on copper sorption in brown earth and red soil,and Freundlich equation(Cs= KfCen) to characterize the sorption behaviors of copper.The results showed that brown earth had stronger ability to absorb Cu.than red soil.Compared to the non-phosphorus system,applied hydroxyapatite could increase capability to absorb copper in both brown earth and red soils,when applied at n(P): n(Cu)]= 1:1.The effect of applied hy...
Keywords:hydroxyapatite  copper  brown earth  red earth  sorption  distribution coefficient  
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