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Optimization of combustion conditions to minimize dioxin emissions
Institution:1. Dept. of Soil Sciences, Faculty of Water and Soil Engineering, Gorgan University of Agricultural Sciences and Natural Resources, Gorgan, Iran;2. Pistachio Research Center, Rafsanjan, Iran;1. Department of Coal Chemistry and Environmental Sciences, Poland;2. Department of Fuels Technology, Faculty of Energy and Fuels, AGH – University of Science and Technology in Kraków, Al. A. Mickiewicza 30, 30-059 Kraków, Poland;3. Výzkumné Energetické Centrum, Technická Univerzita Ostrava, 17 Listopadu 15/2172, 708-33 Ostrava–Poruba, Czech Republic
Abstract:Polychlorinated dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF) may enter an incinerator with the waste, be created in poor combustion or form in post-combustion zones under certain conditions of temperature and oxygen. Tests of MSW burning plants show a wide range of emissions of PCDD and PCDF. Diagnostic tests show the relationship between combustion conditions and the emission of PCDD/DF before and after emission controls. Mixing effectiveness, tightness of control, moisture, furnace and post-furnace temperatures, and the use of lime and reduced temperatures for acid-gas control all have an effect on emissions of trace organics. Carbon monoxide (CO), oxygen, moisture and furnace temperature have been found to be closely related to PCDD/PCDF emissions. By control of temperature and/or oxygen, and the use of CO as an indicator, it is possible to find and maintain optimum combustion conditions so as to minimize dioxins and furans. Plants having acid-gas controls reduce emissions below those achieved by good combustion alone.
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