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微波辐射Bi2O3/沸石-H2O2体系降解废水中的硝基苯
引用本文:张立眉,高建峰,张立成.微波辐射Bi2O3/沸石-H2O2体系降解废水中的硝基苯[J].环境工程学报,2010,4(2):365-372.
作者姓名:张立眉  高建峰  张立成
作者单位:中国铝业山西分公司,河津 043300,中北大学理学院,太原 030051,中国铝业山西分公司,河津 043300
摘    要:研究了微波辐射下,以负载于沸石上的三氧化二铋为催化剂,以双氧水为氧化剂的催化氧化体系处理硝基苯工艺。通过单因素实验法,从反应催化剂负载量、pH、双氧水用量、微波功率、反应时间、催化剂用量等方面初步考察了硝基苯在该体系中的催化氧化效果。在氧化铋负载量3%(质量比),pH=2,2 mL 30%双氧水,火力为中火,催化剂投加量为0.7 g,反应2 min,对降解过程所得的中间产物和终产物进行了分析。结果表明,该体系对硝基苯的去除率能够达到99.2%,COD去除率为73.91%。

关 键 词:催化氧化  硝基苯废水  Bi2O3/沸石  微波

Degradation of nitrobenzene in wastewater with microwave irradiated Bi2O3/zeolite-H2O2 system
Zhang Limei,Gao Jianfeng and Zhang Licheng.Degradation of nitrobenzene in wastewater with microwave irradiated Bi2O3/zeolite-H2O2 system[J].Techniques and Equipment for Environmental Pollution Control,2010,4(2):365-372.
Authors:Zhang Limei  Gao Jianfeng and Zhang Licheng
Institution:Shanxi Brance,Aluminum Corporation of China,Hejin 043300,China,School of Science, North University of China, Taiyuan 030051, China and Shanxi Brance,Aluminum Corporation of China,Hejin 043300,China
Abstract:Under microwave radiation, the Bi2O3 supported on activated carbon was used as catalyst and oxydol as oxidant to form a catalytic oxidative system for the treatment of nitrobenzene wastewater. By single factor experiments , the catalytic oxidation effect of nitrobenzene in the system was preliminarily investigated from the aspects of Bi2O3-loaded amount, initial pH, H2O2 concentration, microwave power, reactive time and amount of Bi2O3 /zeolite. Under the following conditions: Bi2O3 loaded amount 3%(mass ratio), initial pH 2, 30% H2O2 dosage 2 mL, middle power, catalysts dosage 0.7 g and 2 min response time, the intermediate products and final products in the degradation process were analyzed. The results showed that the removal rate of nitrobenzene was up to 99.2% and COD decreased by 73.91%.
Keywords:catalytic oxidation  nitrobenzene wastewater  Bi2O3/zeolite  microwave
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