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Reactions between the SO4·- radical and some common anions in atmospheric aqueous droplets
作者姓名:OUYANG Bin  FANG Hao-jie  ZHU Cheng-zhu  DONG Wen-bo  HOU Hui-qi
作者单位:[1]Laser Flash Photolysis Laboratory, Institute of Environmental Science, Fudan University, Shanghai 200433 China
摘    要:IntroductionThe conversion processes of some atmospheric pollutantsinside the aqueous droplets e .g. clouds , rains and fogspresent interesting topics to discuss . One typical example ofthis kind of pollutants was SO2. It can dissolve into thedroplets rea…

关 键 词:SO4^-  阴离子  大气污染  光解作用  大气环境  光化学烟雾
文章编号:1001-0742(2005)05-0786-03
收稿时间:2004-12-12
修稿时间:2005-03-10

Reactions between the SO4.-radical and some common anions in atmospheric aqueous droplets
OUYANG Bin,FANG Hao-jie,ZHU Cheng-zhu,DONG Wen-bo,HOU Hui-qi.Reactions between the SO4.-radical and some common anions in atmospheric aqueous droplets[J].Journal of Environmental Sciences,2005,17(5):786-788.
Authors:OUYANG Bin  FANG Hao-jie  ZHU Cheng-zhu  DONG Wen-bo and HOU Hui-qi
Institution:Laser Flash Photolysis Laboratory, Institute of Environmental Science, Fudan University, Shanghai 200433, China
Abstract:The rate constants of reactions between the SO4^- radical and some common anions in atmospheric aqueous droplets e.g. Cl^-,NO^-, HSO3^- and HCO3^- were determined using the laser flash photolysis technique.Absorption spectra of SO4^- and the product radicals were also reported.The chloride ion was evaluated among all the anions to be the most efficient scavenger of SO4^-.The results may supply useful information for a better understanding of the vigorous radical-initiated reactions in atmospheric aqueous droplets such as clouds, rains or fogs.
Keywords:sulfate radical  common anions  atmospheric aqueous-phase chemistry  radical chemistry
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