| PbO2/Ti改性电极电催化氧化酸性品红的试验研究 |
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| 引用本文： | 胡锋平,王晓淼,刘占孟. PbO2/Ti改性电极电催化氧化酸性品红的试验研究[J]. 环境科学与技术, 2010, 33(5). DOI: 10.3969/j.issn.1003-6504.2010.05.012 |
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| 作者姓名： | 胡锋平 王晓淼 刘占孟 |
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| 作者单位： | 华东交通大学土木建筑学院,江西,南昌,330013;华东交通大学土木建筑学院,江西,南昌,330013;华东交通大学土木建筑学院,江西,南昌,330013 |
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| 基金项目： | 江西省教育厅科研项目 |
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| 摘 要： | 采用热氧化法制备了PbO2/Ti改性电极,以酸性品红为处理对象,采用未掺杂和掺杂Fe、Ni的改性电极电催化氧化降解酸性品红,比较不同电极的电催化效果,考察电流密度、电解质浓度对电催化氧化处理系统的影响。结果表明:在酸性品红初始浓度为100mg/L,电流密度为75mA/cm2,电解质(Na2SO4)浓度为12g/L的条件下,分别以掺杂Fe和Ni电极为阳极,1h后酸性品红的去除率分别为91.86%和93.04%;Ti/SnO2-Sb2O3/PbO2-Fe和Ti/SnO2-Sb2O3/PbO2-Ni电极,其电催化性能明显优于传统PbO2/Ti电极。
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| 关 键 词： | 电催化氧化 PbO2/Ti电极 改性电极 酸性品红 |
Experimental Study on Electro-catalytic Oxidation of Acid Fuchsin by PbO2/Ti Modified Electrodes |
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| HU Feng-ping,WANG Xiao-miao,LIU Zhan-meng. Experimental Study on Electro-catalytic Oxidation of Acid Fuchsin by PbO2/Ti Modified Electrodes[J]. Environmental Science and Technology, 2010, 33(5). DOI: 10.3969/j.issn.1003-6504.2010.05.012 |
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| Authors: | HU Feng-ping WANG Xiao-miao LIU Zhan-meng |
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| Abstract: | To investigate the effectiveness of Fe-doped PbO2/Ti and Ni-doped PbO2/Ti electrodes comparative studies were carried out for experimental electro-catalytic oxidation of fuchsin. The influencing factors including current density and electrolyte (Na2SO4) concentration were examined. Results showed that removal of acid fuchsin could reach 91.86% by using Fe-doped PbO2/Ti electrode and 93.04% by using Ni-doped electrodes, indicating notably better performance of the modified PbO2/Ti electrodes than the non-modified PbO2/Ti electrode. |
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| Keywords: | electro-catalytic oxidation PbO2/Ti electrode modified electrode acid fuchsin |
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