Study of the solubility and stability of polystyrene wastes in a dissolution recycling process |
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Authors: | María Teresa García Ignacio Gracia Gema Duque Antonio de Lucas Juan Francisco Rodríguez |
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Affiliation: | 1. Department of Chemical Engineering, B.V. Raju Institute of Technology, Narsapur, Medak Dist., 502313, Telangana, India;2. Department of Chemical Engineering, BITS-Pilani Hyderabad Campus, Hyderabad, 500078, Telangana, India;1. High-Performance Materials Institute, Florida A&M University – Florida State University, College of Engineering, Tallahassee, FL, 32310, United States;2. Department of Chemistry, University of Texas Rio Grande Valley, TX 78520, United States;1. Department of Biosystems Engineering, Faculty of Agriculture, University of Tabriz, Tabriz, Iran;2. Microbial Biotechnology Department, Agricultural Biotechnology Research Institute of Iran (ABRII), Agricultural Research, Education, and Extension Organization (AREEO), P.O. Box: 31535-1897, Karaj, Iran;3. Biofuel Research Team (BRTeam), Karaj, Iran;1. Department of Chemical Engineering, BVRIT, Narsapur, Medak Dist., 502313, Telangana, India;2. Department of Chemical Engineering, BITS-Pilani, Hyderabad Campus, Hyderabad, 500078, Telangana, India |
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Abstract: | Dissolution with suitable solvents is one of the cheapest and more efficient processes for polystyrene waste management. In this work the solubility of polystyrene foams in several solvents benzene, toluene, xylene, tetrahydrofuran, chloroform, 1,3-butanediol, 2-butanol, linalool, geraniol, d-limonene, p-cymene, terpinene, phellandrene, terpineol, menthol, eucalyptol, cinnamaldheyde, nitrobenzene, N,N-dimethylformamide and water has been determined.Experimental results have shown that to develop a “green process” the constituents of essential oils, d-limonene, p-cymene, terpinene, phellandrene, are the most appropriate solvents. The action of these solvent does not produce any degradation of polymer chains. The solubility of the polymer in the mentioned solvents at different temperatures has been investigated. The solvent can be easily recycled by distillation. |
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